全文获取类型
收费全文 | 1344篇 |
免费 | 129篇 |
国内免费 | 105篇 |
专业分类
化学 | 1038篇 |
晶体学 | 14篇 |
力学 | 40篇 |
综合类 | 8篇 |
数学 | 190篇 |
物理学 | 288篇 |
出版年
2023年 | 23篇 |
2022年 | 20篇 |
2021年 | 32篇 |
2020年 | 46篇 |
2019年 | 52篇 |
2018年 | 41篇 |
2017年 | 37篇 |
2016年 | 59篇 |
2015年 | 57篇 |
2014年 | 54篇 |
2013年 | 76篇 |
2012年 | 112篇 |
2011年 | 97篇 |
2010年 | 79篇 |
2009年 | 58篇 |
2008年 | 78篇 |
2007年 | 65篇 |
2006年 | 71篇 |
2005年 | 73篇 |
2004年 | 53篇 |
2003年 | 43篇 |
2002年 | 55篇 |
2001年 | 56篇 |
2000年 | 39篇 |
1999年 | 28篇 |
1998年 | 12篇 |
1997年 | 18篇 |
1996年 | 28篇 |
1995年 | 16篇 |
1994年 | 14篇 |
1993年 | 6篇 |
1992年 | 12篇 |
1991年 | 14篇 |
1990年 | 10篇 |
1989年 | 9篇 |
1988年 | 9篇 |
1987年 | 2篇 |
1986年 | 5篇 |
1985年 | 5篇 |
1984年 | 3篇 |
1983年 | 4篇 |
1982年 | 1篇 |
1981年 | 1篇 |
1980年 | 2篇 |
1978年 | 1篇 |
1967年 | 1篇 |
1966年 | 1篇 |
排序方式: 共有1578条查询结果,搜索用时 187 毫秒
101.
傅里叶变换近红外光谱法同时定量分析水溶液中乙醇、果糖和葡萄糖 总被引:6,自引:0,他引:6
利用乙醇、果糖和葡萄糖在波数为14000-7500cm^-1范围内的吸收值,在近红外谱区用偏最小二乘法(PLS)对体系进行建模,并通过内部和外部样品校验确认最佳数据预处理方法。结果表明,乙醇在0.05-0.25L/L,果糖在0.01-0.05g/mL及葡萄糖在0.005-0.009g/mL的范围内外部校验模型较好的分别是在PLS中所用的一阶偏导(平滑点数是5)、二阶偏导(平滑点数是5)和直线消除法的数据预处理方法所建立的模型,其外部校验预测结果的相对误差在2%左右。此方法具有可同时测定不同样品,简便快速及成本低等优点。 相似文献
102.
A new dinuclear Cu(II) complex, [Cu2L(N3)2](ClO4)1.5 (OH)4.5 · 2H2O 0.5C2H5OH (1), of a bis‐macrocyclic ligand, 2,6‐bis(l,4,7,10‐tetraazacyclododecan‐10‐ylmethyl)‐methoxybenzene (L), has been synthesized, characterized and structurally determined by X‐ray diffraction analysis. Complex 1 crystallizes in orthorhombic crystal system, Pca2(l) space group with a = 1.5371(3), b = 1.6641(3), c = 3.0950(6) nm, V = 7.917(3) nm3, Fw = 904.62, Z=8, Dc= 1.529 g/cm3 and final R = 0.0568, wR = 0.1406 for 10410 observed reflections with I≥2σ (I). Both Cu(II) centers in the structure are coordinated by four nitrogen atoms of 1,4,7, 10‐tetraazacyclododecane (cyclen) and a nitrogen donor of the axial azide anion. Each Cu(II) center is in a square‐pyramidal coordination environment, and the intra‐and nearest inter‐molecular Cu? Cu nonbonding distances are 0.9855 and 0.7298 nm, respectively. Variable temperature magnetic susceptibility measurements in the range of 4.2–300 K indicate mat there exists weak intra‐ and inter‐molecular antiferromagnetic coupling between the Cu(II) centers with 27= ?4.2 cm?1 and Θ = ?0.47 K. 相似文献
103.
Jun LIU Hong Ping LI Zhi Min LIU Bu Xing HAN* Hai Ke YAN Center for Molecular Science Institute of Chemistry Chinese Academy of Sciences Beijing 《中国化学快报》2001,(5)
Over the past decade there has been a growing interest in using supercritical fluids (SCFs) to promote reactions and to replace hazardous solvents with environmentally benign solvents, such as supercritical CO2 and H2O. Many reactions in SCFs have been studied1, including polymerization in scCO22. It is known that a small change in the pressure near critical point of a fluid causes a significant change in density-dependent properties such as the solubility parameter, viscosity, and dielect… 相似文献
104.
Jiqing Xu Renzhang Wang Chunxiao Guo Guoyu Yang Qingxin Zeng Weiming Bu Ling Ye Yuguo Fan Guangdi Yang 《中国科学B辑(英文版)》2001,44(2):137-146
A nickel-1,10-phenanthroline complex supported on an octamolybdate, [(Ni(phen)2
2(ξ-Mo8O26)], has been hydrothermally synthesized with MoO3, H2MoO4, Ni(OAc)2 6H3O and 1,10-phenathroline (1,10-phen) as raw materials. The crystals of the compound belong to monoclinic P21/n space group,a = 1.2952(2),b = 1.6659(10),c = 1.3956(12) nm, β =106.273(8)°,V = 2.8906(5) nm3,Z = 2. 5604 observable reflections (I >2σ(I)) were used for structure resolution and refinements to converge to finalR
1 = 0.0414,wR
2 = 0.0815. The result of structure determination shows that the compound contains octamolybdate possessing a novel structure
type (named as ξ-isomer). The feature of ξ-[Mo8O26]4- is that it is composed of Mo6O6 ring and two MoO6 octahedral located at cap positions on opposite faces. The Mo6O6 ring contains two octahedral and four trigonal-bipyramidal MoVI atoms. Each ξ-[Mo8O26]4- unit is bonded with two [Ni(phen)2]2+ through terminal oxygen atoms of octahedral and neighbouring trigonal-bipyramidal Mo atom in the Mo6O6 ring. IR and UV-Vis spectra of the compound were measured and its electronic structure was studied by EHMO method. 相似文献
105.
A theoretical scheme is presented which is based on an activation model for calculating the rate of the electron- exchange reaction between transition metal complexes in aqueous solution and applies to Co(H2O)6 2+/3+ electron transfer system. The activation parameter and activation energy of the system are obtained via the activation model. The slopes of the potential energy surfaces (curves) of the reacting system at the separated reactants are calculated from the fitted potential energy curves. The coupling matrix element is determined by using the perturbation theory and numerical integral method. Theoretical rate constants are obtained for the system at both UHF/6-311G and UMP2/6-311G levels. The agreement of the theoretical results with experimetal values is excellent. This fact indicates the scheme proposed is feasible and accurate in studying the self- exchange eletron transfer reaction. 相似文献
106.
107.
Let Q G denote the signless Laplacian matrix of a graph G. An eigenvalue μ of Q G is said to be a main Q-eigenvalue of G if μ has an eigenvector which is not orthogonal to an all-ones vector e. We give some basic properties of main Q-eigenvalues. For a graph G of order n, G is called Q-controllable if G has n distinct main Q-eigenvalues. We show that a graph H is generalized Q-cospectral with a Q-controllable G if and only if H is Q-controllable and there exists a unique rational orthogonal matrix R such that R e = e, Q H = R ? Q G R. 相似文献
108.
Let X be a Banach space. We show that each m : ? \ {0} → L (X ) satisfying the Mikhlin condition supx ≠0(‖m (x )‖ + ‖xm ′(x )‖) < ∞ defines a Fourier multiplier on B s p,q (?; X ) if and only if 1 < p < ∞ and X is isomorphic to a Hilbert space; each bounded measurable function m : ? → L (X ) having a uniformly bounded variation on dyadic intervals defines a Fourier multiplier on B s p,q (?; X ) if and only if 1 < p < ∞ and X is a UMD space. (© 2005 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim) 相似文献
109.
Changjiang Bu 《Journal of Applied Mathematics and Computing》2006,22(3):255-265
Let R be a PID,chR = 2,n > 1, Mn(R) be then xn full matrix algebra over R.f denotes any invertible linear map preserving {1}-inverses from Mn(R) to itself. In this paper, we have proven thatf is an invertible linear map on Mn(R) preserving {1}-inverses if and only iff satisfies any one of the following two conditions: (i) there exists a matrixP ? GL n(R) such thatf(A) =PAP ?1 for allA ? M n(R), (ii) there exists a matrixP ? GL n(R) such thatf(A) =PA t P?1 forA ? M n(R). 相似文献
110.